LAUSR

The synthesis of electrocatalysts consisting of selectively functionalized parts is an effective strategy to prepare nonprecious electrocatalysts with excellent performance for oxygen evolution reaction (OER). Herein, we synthesized core-shell structured ZIF67@ZIF8 and converted it into Co decorated porous carbons (CS-Co/Cs) consisting of the ZIF67 derived uniformly dispersed Co nanoparticles encapsulated in graphitic carbon as cores and the ZIF8 derived porous carbon as shells. Compared to individual ZIF67 derived samples (Co/Cs), the unique structure of CS-Co/Cs leads to the larger surface area and more hydrophilic surface, both of which facilitate the mass transfer, contributing to the enhanced OER performance. The optimized CS-Co/C sample presents the low overpotential of 290 mV to deliver 10 mA cm-2 toward OER in 1 M KOH, which is among the best of the reported nonprecious OER electrocatalysts. The CS-Co/C exhibits no obvious current attenuation at 1.53 V for 30 000 s, demonstrating its robust stability.