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Flower-Like Molybdenum Disulfide for Polarity-Triggered Accumulation/Release of Small Molecules.

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Flower-like molybdenum disulfide (MoS2) with rich edge sites has been prepared by the hydrothermal method. The edge sites possess polarity due to the noncentrosymmetric Mo-S on exposed (100) facets and… Click to show full abstract

Flower-like molybdenum disulfide (MoS2) with rich edge sites has been prepared by the hydrothermal method. The edge sites possess polarity due to the noncentrosymmetric Mo-S on exposed (100) facets and thus show a strong electrostatic attraction toward polar species. The flower-like MoS2 can be used as small-molecule carriers for the model drug, Rhodamine B (RhB). The results prove that flower-like MoS2 have fast adsorption kinetics and perform a switchable accumulation/release with response to the solvent polarity. An outstanding reusability can be found in flower-like MoS2 due to little cargo retention, and the recycle of adsorption can be repeated 100 times with above 88.5% of the adsorption capacity retained. The flower-like MoS2 with solvent polarity-triggered loading/release can be extended to controlled release and color switch of display.

Keywords: flower like; like mos2; polarity; molybdenum disulfide; like molybdenum; release

Journal Title: ACS applied materials & interfaces
Year Published: 2017

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