Photo by arthurlfranklin from unsplash
Self-assembly of resorcin[4]arene-based coordination cages involving more than two resorcin[4]arenes poses significant challenges for the requirements of suitable functionalized resorcin[4]arene ligands and metals. Here, we report an unusual example of… Click to show full abstract
Self-assembly of resorcin[4]arene-based coordination cages involving more than two resorcin[4]arenes poses significant challenges for the requirements of suitable functionalized resorcin[4]arene ligands and metals. Here, we report an unusual example of a metal-coordinated, resorcin[4]arene-based molecular trimer (1-NO3), composed of three resorcin[4]arenes and three Cd(II) cations. In particular, 1-NO3 features efficient and selective removal of environmentally toxic dichromate (Cr2O72-) anions. Moreover, the Knoevenagel condensation reaction was also explored by using 1-NO3 as an efficient heterogeneous catalyst.
Journal Title: ACS applied materials & interfaces
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!