LAUSR

Vertically aligned Pd nanofiber arrays (NFAs) have been prepared at the liquid-liquid interface between redox-active ionic liquid (RAIL) and water (W) via a template-free manner. The RAIL with high hydrophobicity, (ferrocenylmethyl)dodecyldimethylammonium bis(nonafluorobutanesulfonyl) amide, plays dual roles of reducing agent for Pd precursor ions and the hydrophobic liquid phase simultaneously, and the RAIL|W interface has been utilized as the formation site for the spontaneous growth of Pd NFAs. The Pd NFAs consist of three parts: layers formed by partly connected particles on the top, NFAs in the middle, and firm sheet-like layers on the bottom. Owing to the top and bottom supporting layers, the anti-deformation ability and durability of the Pd NFAs with a length reaching several micrometers are enhanced. A possible mechanism for the formation of the Pd NFAs has been discussed. The Pd NFAs show a good stability and a higher electrocatalytic activity toward ethanol oxidation reaction than a commercial Pd/C catalyst. The present study provides a new strategy for the template-free and spontaneous formation of Pd NFAs.