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Nanosized MoSe2@Carbon Matrix: A Stable Host Material for the Highly Reversible Storage of Potassium and Aluminum Ions.

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Owing to their low-cost and abundant reserves relative to conventional lithium-ion batteries (LIBs), potassium-ion batteries (PIBs) and aluminum-ion batteries (AIBs) have shown appealing potential for electrochemical energy storage, but progress… Click to show full abstract

Owing to their low-cost and abundant reserves relative to conventional lithium-ion batteries (LIBs), potassium-ion batteries (PIBs) and aluminum-ion batteries (AIBs) have shown appealing potential for electrochemical energy storage, but progress so far has been limited by the lack of suitable electrode materials. In this work, we demonstrated a facile strategy to achieve highly reversible potassium and aluminum ions storage in strongly coupled nanosized MoSe2@carbon matrix, induced through an ion complexation strategy. We present a broad range of electrochemical characterization of the synthesized product which exhibits high specific capacities, good rate capability and excellent cycling stability towards PIBs and AIBs. Through a series of systematic ex-situ X-ray photoelectron spectroscopy (XPS) characterizations and density functional theory (DFT) calculations, the Al3+ intercalation mechanism of MoSe2 based AIBs are elucidated. Moreover, both the assembled PIBs and AIBs worked well when exposed to low and high temperatures within the range of -10 to 50 ℃, promising for the energy storage devices in the harsh environment. The present study provides new insights on exploration of MoSe2 as high-performance electrode materials for PIBs and AIBs.

Keywords: storage; aluminum ions; potassium aluminum; highly reversible; mose2 carbon; nanosized mose2

Journal Title: ACS applied materials & interfaces
Year Published: 2019

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