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SnSe2 Nanoparticles Chemically Embedded in Carbon Shell for High Rate Sodium Ion Storage.

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The development of advanced anode materials is crucial to enhance the performance of sodium ion batteries (SIBs). In this study, SnSe2 nanoparticles chemically embedded in carbon shell (SnSe2@C) were fabricated… Click to show full abstract

The development of advanced anode materials is crucial to enhance the performance of sodium ion batteries (SIBs). In this study, SnSe2 nanoparticles chemically embedded in carbon shell (SnSe2@C) were fabricated from Sn-organic frameworks, and evaluated as an anode material for SIBs. The structural characterization demonstrated that there existed C-Sn chemical bonds between the SnSe2 nanoparticles and carbon shell, which could strongly anchor SnSe2 nanoparticles to carbon shell. Such structure can not only facilitate charge transfer, but also ensure the structural stability of SnSe2@C electrode. In addition, carbon shell also helped to the dispersion of SnSe2 nanoparticles, thus offering more redox active sites for Na+ storage. The as-prepared SnSe2@C nanocomposite could deliver good cycling stability and a superior rate capability of 324 mA h g-1 at 2 A g-1 for SIBs.

Keywords: sodium ion; carbon shell; snse2 nanoparticles

Journal Title: ACS applied materials & interfaces
Year Published: 2019

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