Developing new cathode-active materials for rechargeable battery is important to fulfill the growing demands of energy transformation, storage, and utilization. Zeolitic transition metal oxides based on vanadomolybdate, constructed by pentagon… Click to show full abstract
Developing new cathode-active materials for rechargeable battery is important to fulfill the growing demands of energy transformation, storage, and utilization. Zeolitic transition metal oxides based on vanadomolybdate, constructed by pentagon metal-oxygen clusters as building blocks and metal ions as linkers in a trigonal symmetry, are good candidates for cathodes of Na rechargeable battery. The material is activated via amorphization of the crystal structure in the ab plane during discharging process with keeping the molecular structure of the building blocks stable, which causes high specific capacity and good cycle performance.
Journal Title: ACS applied materials & interfaces
Year Published: 2020
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