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TiO2 Nanotube Arrays Formed on Ti Meshes with Periodically Arranged Holes for Flexible Dye-Sensitized Solar Cells

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Vertically oriented TiO2 nanotubes (VOTNs) were prepared on Ti mesh substrates with periodically arranged holes by electrochemical anodization, which were then used as the photoanodes for flexible dye-sensitized solar cell… Click to show full abstract

Vertically oriented TiO2 nanotubes (VOTNs) were prepared on Ti mesh substrates with periodically arranged holes by electrochemical anodization, which were then used as the photoanodes for flexible dye-sensitized solar cell (DSSC) fabrication. The VOTNs were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The effects of the anodization on the physical features of the VOTNs, such as nanotube diameter, wall thickness, and nanotube length, were studied in detail. The Ti mesh is an ideal candidate for DSSC substrates due to its highly bending ability under external force. The photo-to-electric conversion efficiency (η) of the mesh-VOTN-based DSSCs is dependent on the TiO2 nanotube length, which can achieve an efficiency of 2.66% at 100 mW cm–2 under AM 1.5 simulated full light when the nanotube length is ∼18 μm. The DSSC performance dependence on the Ti mesh geometry and the incident angle of the illuminated light were characterized by current density vs voltage (I–V) measureme...

Keywords: sensitized solar; flexible dye; periodically arranged; tio2 nanotube; arranged holes; dye sensitized

Journal Title: ACS Applied Nano Materials
Year Published: 2019

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