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Effect of Ligand Electronics on the Reversible Catalytic Hydrogenation of CO2 to Formic Acid Using Ruthenium Polyhydride Complexes: A Thermodynamic and Kinetic Study

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Hydrogenation of CO2 to formic acid or formates is often carried out using catalysts of the type H4Ru(PR3)3 (1). These catalysts are also active for the reverse reaction, i.e., the… Click to show full abstract

Hydrogenation of CO2 to formic acid or formates is often carried out using catalysts of the type H4Ru(PR3)3 (1). These catalysts are also active for the reverse reaction, i.e., the decomposition of...

Keywords: co2 formic; hydrogenation co2; formic acid

Journal Title: ACS Catalysis
Year Published: 2020

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