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Fe-Catalyzed Aziridination Is Governed by the Electron Affinity of the Active Imido-Iron Species

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Aziridination has very recently been found to be catalyzed by heme and nonheme Fe enzymes, opening the way to biotechnological developments. However, its mechanism is not fully understood owing to… Click to show full abstract

Aziridination has very recently been found to be catalyzed by heme and nonheme Fe enzymes, opening the way to biotechnological developments. However, its mechanism is not fully understood owing to ...

Keywords: catalyzed aziridination; affinity active; aziridination; electron affinity; governed electron; aziridination governed

Journal Title: ACS Catalysis
Year Published: 2020

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