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Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand

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Syntheses and catalytic application of rhodium complexes having a pincer-type group 13 metallylene ligand are reported. The PGaIP–Rh complex exhibited high chemoselectivity for hydrosilylation of n... Click to show full abstract

Syntheses and catalytic application of rhodium complexes having a pincer-type group 13 metallylene ligand are reported. The PGaIP–Rh complex exhibited high chemoselectivity for hydrosilylation of n...

Keywords: type group; metallylene ligand; rhodium; group metallylene; pincer type

Journal Title: ACS Catalysis
Year Published: 2020

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