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Alkene Epoxidations with H2O2 over Groups 4–6 Metal-Substituted BEA Zeolites: Reactive Intermediates, Reaction Pathways, and Linear Free-Energy Relationships

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Rates and selectivities for alkene epoxidations depend sensitively on the identity of the active metal center for both heterogeneous and homogeneous catalysts. While group 6 metals (Mo, W) have gre... Click to show full abstract

Rates and selectivities for alkene epoxidations depend sensitively on the identity of the active metal center for both heterogeneous and homogeneous catalysts. While group 6 metals (Mo, W) have gre...

Keywords: metal substituted; alkene epoxidations; metal; groups metal; epoxidations h2o2; h2o2 groups

Journal Title: ACS Catalysis
Year Published: 2020

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