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Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization

A series of chiral-at-metal aluminum complexes have been synthesized using chiral catam ligands. Reactivity studies demonstrate the importance of alkoxide bulkiness and complex chirality in inducin... Click to show full abstract

A series of chiral-at-metal aluminum complexes have been synthesized using chiral catam ligands. Reactivity studies demonstrate the importance of alkoxide bulkiness and complex chirality in inducin...

Keywords: chirality induced; catalyst aggregation; aluminum; induced catalyst; using chiral

Journal Title: ACS Catalysis
Year Published: 2021

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