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Cobalt-Hydride-Catalyzed Hydrosilylation of 3-Alkynes Accompanying π-Bond Migration

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We describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying π-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine lig... Click to show full abstract

We describe a protocol for cobalt-catalyzed hydrosilylation of 3-alkynes with accompanying π-bond migration. Mechanistic studies indicate that (i) cobalt(I)-hydride bearing a bulky bisphosphine lig...

Keywords: alkynes accompanying; hydrosilylation alkynes; catalyzed hydrosilylation; bond migration; accompanying bond; cobalt hydride

Journal Title: ACS Catalysis
Year Published: 2021

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