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A Highly Reactive Chromium(V)–Oxo TAML Cation Radical Complex in Electron Transfer and Oxygen Atom Transfer Reactions

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We report the synthesis, characterization, and electron-transfer (ET) oxidation reactivity of a chromium(V)–oxo TAML cation radical complex binding Sc3+ ion, {[CrV(O)(TAML•+)]-Sc3+}3+ (2-Sc). Its p... Click to show full abstract

We report the synthesis, characterization, and electron-transfer (ET) oxidation reactivity of a chromium(V)–oxo TAML cation radical complex binding Sc3+ ion, {[CrV(O)(TAML•+)]-Sc3+}3+ (2-Sc). Its p...

Keywords: taml cation; oxo taml; transfer; taml; chromium oxo; electron transfer

Journal Title: ACS Catalysis
Year Published: 2021

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