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Nature of the Active Catalyst in the Hafnium-Pyridyl Amido-Catalyzed Alkene Polymerization

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We report the true nature of active catalysts in the polymerization of 1-octene catalyzed by the racemic hafnium-pyridyl amido cation (I). Chromophore quench-labeling (CQL) studies reveal that only... Click to show full abstract

We report the true nature of active catalysts in the polymerization of 1-octene catalyzed by the racemic hafnium-pyridyl amido cation (I). Chromophore quench-labeling (CQL) studies reveal that only...

Keywords: pyridyl amido; hafnium pyridyl; nature active; polymerization

Journal Title: ACS Catalysis
Year Published: 2021

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