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Enantioselective α-Fluorination and α-Chlorination of N-Acyl Pyrazoles Catalyzed by a Non-C2-Symmetric Chiral-at-Rhodium Catalyst

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185. Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Metal Complexes: Synthesis and Asymmetric Catalysis: S. Brunen, Y. Grell, P. S. Steinlandt, K. Harms, E. Meggers, Molecules 2021, 26, 1822. 184. Efficient Amination of… Click to show full abstract

185. Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Metal Complexes: Synthesis and Asymmetric Catalysis: S. Brunen, Y. Grell, P. S. Steinlandt, K. Harms, E. Meggers, Molecules 2021, 26, 1822. 184. Efficient Amination of Activated and Non-Activated C(sp)-H Bonds with Simple IronPhenanthroline Catalyst: L. Jarrige, Z. Zhou, M. Hemming, E. Meggers, Angew. Chem. Int. Ed. 2021, 60, 6314-6319 (Synfacts 2021, 17, 0377).

Keywords: enantioselective fluorination; fluorination chlorination; pyrazoles catalyzed; chlorination acyl; acyl pyrazoles; catalyst

Journal Title: ACS Catalysis
Year Published: 2021

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