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Quinuclidine-mediated electrochemical oxidation of glycopyranosides provides C3-ketosaccharides with high selectivity and good yields. The method is a versatile alternative to Pd-catalyzed or photochemical oxidation and is complementary to the 2,2,6,6-tetramethylpiperidine… Click to show full abstract
Quinuclidine-mediated electrochemical oxidation of glycopyranosides provides C3-ketosaccharides with high selectivity and good yields. The method is a versatile alternative to Pd-catalyzed or photochemical oxidation and is complementary to the 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)-mediated C6-selective oxidation. Contrary to the electrochemical oxidation of methylene and methine groups, the reaction proceeds without oxygen.
Keywords:
electrochemical oxidation;
oxidation;
site selective;
oxidation glycosides;
selective electrochemical
Journal Title: ACS Catalysis
Year Published: 2023
Link to full text (if available)
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Journal Title: ACS Catalysis
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!