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Ni–Pd binary nanoclusters are reported for the activation of the C–O bond for Suzuki–Miyaura cross-coupling of bioactive heterocycle-tethered sterically hindered aryl carbonates with aryl boronic acids. The reaction does not… Click to show full abstract
Ni–Pd binary nanoclusters are reported for the activation of the C–O bond for Suzuki–Miyaura cross-coupling of bioactive heterocycle-tethered sterically hindered aryl carbonates with aryl boronic acids. The reaction does not take place in the presence of either the Pd or Ni salts/complexes or the individual Pd or Ni nanoparticles, indicating ensembling cooperativity between the Pd and Ni nanoparticles in activating the C–O bond.
Keywords:
bond;
sterically hindered;
bioactive heterocycle;
tethered sterically;
heterocycle tethered;
suzuki miyaura
Journal Title: ACS Catalysis
Year Published: 2017
Link to full text (if available)
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Journal Title: ACS Catalysis
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!