Combinations of Ni(acac)2 with phosphine ligands were found to catalyze the regioselective hydroboration of N-heteroarenes with pinacolborane, affording N-borylated 1,4-reduction products. Preliminary mechanistic studies have focused on the isolation and… Click to show full abstract
Combinations of Ni(acac)2 with phosphine ligands were found to catalyze the regioselective hydroboration of N-heteroarenes with pinacolborane, affording N-borylated 1,4-reduction products. Preliminary mechanistic studies have focused on the isolation and study of potential intermediates in the catalytic cycle.
Keywords:
regioselective hydroboration;
catalyzed regioselective;
hydroboration heteroarenes;
nickel catalyzed
Journal Title: ACS Catalysis
Year Published: 2018
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Journal Title: ACS Catalysis
Year Published: 2018
Link to full text (if available)
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recommendations!