Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving… Click to show full abstract
Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal–ligand cooperation of the manganese pincer complex, is proposed based on NMR studies and relevant stoichiometric reactions.
Keywords:
deoxygenative hydrogenation;
hydrogenation amides;
metal;
ligand cooperation;
metal ligand;
manganese pincer
Journal Title: ACS Catalysis
Year Published: 2018
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Journal Title: ACS Catalysis
Year Published: 2018
Link to full text (if available)
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recommendations!