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The Impact of Oxygen on Leading and Emerging Ru-Carbene Catalysts for Olefin Metathesis: An Unanticipated Correlation Between Robustness and Metathesis Activity

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The impact of O2 on olefin metathesis promoted by Ru-NHC and Ru-CAAC catalysts is examined (NHC = N-heterocyclic carbene; CAAC = cyclic alkyl amino carbene). An atmosphere of 8% O2… Click to show full abstract

The impact of O2 on olefin metathesis promoted by Ru-NHC and Ru-CAAC catalysts is examined (NHC = N-heterocyclic carbene; CAAC = cyclic alkyl amino carbene). An atmosphere of 8% O2 in Ar is found t...

Keywords: leading emerging; impact oxygen; olefin metathesis; oxygen leading; metathesis

Journal Title: ACS Catalysis
Year Published: 2019

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