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Highly Selective Synthesis of 1,3-Enynes, Pyrroles, and Furans by Manganese(I)-Catalyzed C–H Activation

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A highly selective Mn(I)-catalyzed alkenylation of arenes and heteroarenes with 1,3-diynes is described. The reported transformation overcomes regio-, chemo-, and stereoselectivity challenges assoc... Click to show full abstract

A highly selective Mn(I)-catalyzed alkenylation of arenes and heteroarenes with 1,3-diynes is described. The reported transformation overcomes regio-, chemo-, and stereoselectivity challenges assoc...

Keywords: synthesis enynes; highly selective; furans manganese; selective synthesis; enynes pyrroles; pyrroles furans

Journal Title: ACS Catalysis
Year Published: 2019

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