Enantioselective conjunctive cross-coupling with propargylic carbonates affords (β-boryl allenes as the reaction product. The reaction is found to proceed through the intermediacy of dimethoxyboronate complexes that are generated in situ… Click to show full abstract
Enantioselective conjunctive cross-coupling with propargylic carbonates affords (β-boryl allenes as the reaction product. The reaction is found to proceed through the intermediacy of dimethoxyboronate complexes that are generated in situ by a strain-induced ligand exchange reaction.
Keywords:
conjunctive cross;
catalytic enantioselective;
propargylic carbonates;
coupling propargylic;
cross coupling
Journal Title: ACS catalysis
Year Published: 2019
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Journal Title: ACS catalysis
Year Published: 2019
Link to full text (if available)
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recommendations!