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Stereoselective Lactide Polymerization: the Challenge of Chiral Catalyst Recognition

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A model for stereoselective ring opening polymerization (ROP) of rac-lactide promoted by chiral aluminum systems is reported based on DFT calculations. The mechanism of enantiomorphic site control ... Click to show full abstract

A model for stereoselective ring opening polymerization (ROP) of rac-lactide promoted by chiral aluminum systems is reported based on DFT calculations. The mechanism of enantiomorphic site control ...

Keywords: lactide polymerization; polymerization; polymerization challenge; challenge chiral; chiral catalyst; stereoselective lactide

Journal Title: ACS Catalysis
Year Published: 2020

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