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Hydroxide-Induced Degradation of Olefin Metathesis Catalysts: A Challenge for Metathesis in Alkaline Media

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Hydroxide ion is shown to be a potent disruptor of Ru-catalyzed olefin metathesis, in a study of the Hoveyda catalyst HII. Addition of [NnBu4][OH] immediately terminates metathesis via HII, an… Click to show full abstract

Hydroxide ion is shown to be a potent disruptor of Ru-catalyzed olefin metathesis, in a study of the Hoveyda catalyst HII. Addition of [NnBu4][OH] immediately terminates metathesis via HII, an effe...

Keywords: hydroxide induced; induced degradation; degradation olefin; olefin metathesis; metathesis catalysts; metathesis

Journal Title: ACS Catalysis
Year Published: 2020

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