LAUSR

As a new example of intrinsically water-triggered phenomena, we report underwater dehydration of the statistical copolymers synthesized from triethanolamine borate (TEAB) methacrylate and styrene (St) induced by the hydrolysis of the pendant TEAB group. TEAB possesses high polarity owing to its internal Lewis adduct structure, which is lost by hydrolysis to triethanolamine (TEA) with a lower dipole moment. Therefore, the hydration of the copolymers became unfavorable through the hydrolysis of the pendant TEAB to TEA, despite polyol formation, and through a hydrophobic interaction based on St moieties becoming alternatively dominant. The dehydration behavior of the copolymers, along with the hydrolysis of the pendant TEAB group, was systematically investigated. The water solubility of the copolymers was found to be dependent on the gradient of the hydrolysis equilibrium of TEAB on the side chains and was the lowest for the TEA state. These findings offer a novel concept toward designing water-responsive materials.