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A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated… Click to show full abstract
A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated polycarbazoles with high porosities and promising CO2 storage abilities. This innovative approach constitutes a new direction for the development of novel nanoporous polymer frameworks through sustainable solid-state assembly pathways, and may open up new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.
Journal Title: ACS Macro Letters
Year Published: 2017
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