LAUSR

The reversible surface patterns with fluorescence and topography can possibly enable information recording and reading and provide an important alternative to realize the higher information security. We demonstrated a reversible dual-pattern with simultaneously responsive fluorescence and topography using an anthracene (AN) and naphthalene diimide (NDI) containing copolymer (PAN-NDI-BA) as the skin layer, in which the reversible photodimerization of AN can simultaneously control the cross-linking and CT interaction between AN and NDI. Upon irradiation with UV light and thermal treatment, the resulting pattern assumes a reversible change between smooth and wrinkled states, and its fluorescence changes reversibly from red to white to blue-green. The smart surfaces with dynamic hierarchical wrinkles and fluorescence were achieved by selective irradiation with photomasks and can be employed for potential applications in smart displays and anticounterfeiting.