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Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition–retroelectrocyclization (CA–RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ)… Click to show full abstract
Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition–retroelectrocyclization (CA–RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties. The resulting thin films showed potent redox activities and Ag+ ion sensing ability due to the formed CT chromophores.
Keywords:
thin films;
layer layer;
layer;
covalent layer;
cycloaddition retroelectrocyclization
Journal Title: ACS Macro Letters
Year Published: 2018
Link to full text (if available)
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Journal Title: ACS Macro Letters
Year Published: 2018
Link to full text (if available)
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recommendations!