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Highly Anisotropic Glassy Polystyrenes Are Flexible

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We show that stretching polystyrene melts at a rate faster than the inverse Rouse time, followed by rapid quenching below the glass transition temperature, results in a material that is… Click to show full abstract

We show that stretching polystyrene melts at a rate faster than the inverse Rouse time, followed by rapid quenching below the glass transition temperature, results in a material that is flexible and remains so for at least six months. Oriented micro/nanofibers are observed in the flexible samples after the mechanical tests. The fibers are probably related to the highly aligned molecules in melt stretching. At room temperature, a tensile strength over 300 MPa has been achieved for the flexible polystyrenes.

Keywords: glassy polystyrenes; anisotropic glassy; highly anisotropic; polystyrenes flexible

Journal Title: ACS Macro Letters
Year Published: 2018

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