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Novel Strategy for Fabricating Multilayer Porous Membranes with Varying Porosity

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CO2-assisted polymer compression (CAPC) is a method for fabricating porous polymer materials in which the polymer is plasticized with CO2 and then pressed. In this work, a two-step molding method… Click to show full abstract

CO2-assisted polymer compression (CAPC) is a method for fabricating porous polymer materials in which the polymer is plasticized with CO2 and then pressed. In this work, a two-step molding method is adapted, and a porous membrane with multiple layers of varying porosity is fabricated by laminating sheets of a single starting material. A model is constructed in which the expansion owing to CO2 and compression reflected by the longitudinal elastic modulus are considered. The model is constructed based on a two-layer experiment and extended to three layers. From the model simulation, the conditions for fabricating a multilayer porous polymer membrane with three layers of varying porosity (0.6, 0.5, and 0.4) and identical thickness (0.6 mm) are calculated. Finally, a porous membrane with varying porosity is fabricated based on the simulated design.

Keywords: multilayer porous; porosity; strategy fabricating; fabricating multilayer; varying porosity; novel strategy

Journal Title: ACS Omega
Year Published: 2020

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