LAUSR

In this work, well-dispersed fumed SiO2/cis-1,4-polyisoprene rubber (IR) masterbatch was first obtained through an effective wet mixing method, and the properties of the corresponding vulcanizate were studied. Before curing with activator and sulfur, IR solution was blended and co-coagulated with SiO2 suspension modified by bis(3-trimethoxysilypropyl) tetrasulfide in n-hexane. The modification of TESPT imparted evenly distributed SiO2 particles in IR and improved interfacial binding among SiO2 and IR. Hence, the prepared compound presented better processability and the corresponding vulcanizate presented higher physical performance, including higher tensile strength, lower heat buildup, and better fatigue resistance than that prepared in the dry mixing method. Additionally, higher wet skid resistance and lower rolling resistance could be observed in fabricated SiO2/IR vulcanizate. The employed wet mixing method is economical and efficient, which is promising in preparing rubber composites with comprehensive performance.