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Noncatalyzed, regio- and stereoselective hypochlorite oxidation of 3-aminothieno[2,3-b]pyridine-2-carboxamides is presented. Unexpectedly, the oxidation proceeded by different mechanistic pathways, and different products were formed, depending on the nature of solvents used.… Click to show full abstract
Noncatalyzed, regio- and stereoselective hypochlorite oxidation of 3-aminothieno[2,3-b]pyridine-2-carboxamides is presented. Unexpectedly, the oxidation proceeded by different mechanistic pathways, and different products were formed, depending on the nature of solvents used. A possible mechanism, the structure of products, kinetics and dynamics of intramolecular processes, and biological activity of products are discussed.
Keywords:
aminothieno pyridine;
pyridine;
pyridine carboxamide;
unusual oxidative;
oxidative dimerization;
dimerization aminothieno
Journal Title: ACS Omega
Year Published: 2021
Link to full text (if available)
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Journal Title: ACS Omega
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!