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Potential End-Use of a Europium Binary Photoluminescent Ink for Anti-Counterfeiting Security Documents

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Composed of two europium complexes doped in polyvinyl butyral as the host material, a novel photoluminescent ink has been formulated by synthesizing Eu(FAC)3Phen as a red luminescent down-shifting emitter and… Click to show full abstract

Composed of two europium complexes doped in polyvinyl butyral as the host material, a novel photoluminescent ink has been formulated by synthesizing Eu(FAC)3Phen as a red luminescent down-shifting emitter and employing SrAl2O4:Eu, Dy as a long persistent green phosphor. Both emitters are incorporated to design a photoluminescent ink with binary emission under a single UV excitation wavelength, where a red light is emitted when exposed under 325 nm, subsequently becoming green upon the UV light being switched off. The concept presented here is unequivocally distinct from the classical dual-mode emission, which requires a second extra near-infrared excitation around 980 nm to produce a binary luminescence. This work demonstrates the effortlessness of using one UV excitation for dual-mode visible emission while rendering the counterfeiting of confidential documents more onerous.

Keywords: end use; europium; potential end; photoluminescent ink; photoluminescent

Journal Title: ACS Omega
Year Published: 2021

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