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Critical Assessment of the Sustainability of Deep Eutectic Solvents: A Case Study on Six Choline Chloride-Based Mixtures

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An outline of the advantages, in terms of sustainability, of Deep Eutectic Solvents (DESs) is provided, by analyzing some of the most popular DESs, obtained by the combination of choline… Click to show full abstract

An outline of the advantages, in terms of sustainability, of Deep Eutectic Solvents (DESs) is provided, by analyzing some of the most popular DESs, obtained by the combination of choline chloride, as a hydrogen bond acceptor, and six hydrogen bond donors. The analysis is articulated into four main issues related to sustainability, which are recurrently mentioned in the literature, but are often taken for granted without any further critical elaboration, as the prominent green features of DESs: their low toxicity, good biodegradability, renewable sourcing, and low cost. This contribution is intended to provide a more tangible, evidence-based evaluation of the actual green credentials of the considered DESs, to reinforce or question their supposed sustainability, also in mutual comparison with one another.

Keywords: deep eutectic; sustainability deep; sustainability; choline chloride; eutectic solvents

Journal Title: ACS Omega
Year Published: 2022

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