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Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates

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A new bambusuril derivative, (H)BU[6], lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6]. (H)BU[6] is attractive… Click to show full abstract

A new bambusuril derivative, (H)BU[6], lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6]. (H)BU[6] is attractive for use as a starting compound for the preparation of other bambusuril derivatives, which was demonstrated via propargylation and the copper-catalyzed click reaction performed on the macrocycle.

Keywords: post macrocyclization; bambusurils post; macrocyclization modification; unsubstituted bambusurils; modification versatile; versatile intermediates

Journal Title: ACS Omega
Year Published: 2018

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