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Facile Synthesis of an Organic Solid State Near-Infrared-Emitter with Large Stokes Shift via Excited-State Intramolecular Proton Transfer

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An organic solid-state near-infrared (NIR)-emitter (λem = 738 nm) exhibiting large Stokes shift (Δλ = 293 nm) through the excited-state intramolecular proton transfer phenomenon has been synthesized and characterized. The… Click to show full abstract

An organic solid-state near-infrared (NIR)-emitter (λem = 738 nm) exhibiting large Stokes shift (Δλ = 293 nm) through the excited-state intramolecular proton transfer phenomenon has been synthesized and characterized. The present discovery points to the possibility of achieving a new family of solid-state NIR emitters starting from simple aldehyde and amine precursors.

Keywords: state; solid state; large stokes; near infrared; organic solid; state near

Journal Title: ACS Omega
Year Published: 2018

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