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Reaction of α-methylstyrene in the presence of HI gas and methyl p-tolyl ketone selectively resulted in an internal olefinic trimer. We revealed that the ketones with the stabilization of the… Click to show full abstract
Reaction of α-methylstyrene in the presence of HI gas and methyl p-tolyl ketone selectively resulted in an internal olefinic trimer. We revealed that the ketones with the stabilization of the protonated state were efficient to give the corresponding trimers, whereas the other ketones gave the usual indane compound. From the investigation for the mechanistic path, we found that the trimer is a kinetic product and that indane is a thermodynamic product.
Keywords:
internal olefinic;
gas;
olefinic trimer;
formation internal;
selective formation
Journal Title: ACS Omega
Year Published: 2018
Link to full text (if available)
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Journal Title: ACS Omega
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!