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Vinylsilanes in Highly Diastereo- and Regio-Selective Synthesis of Dihydropyrans

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Borontrifluoride etherate (BF3·OEt2) can be efficiently used for the synthesis of dihydropyrans from triethylsilyl homoallylic alcohols and aldehydes in good yields. The reaction is highly diastereo- and regio-selective. Click to show full abstract

Borontrifluoride etherate (BF3·OEt2) can be efficiently used for the synthesis of dihydropyrans from triethylsilyl homoallylic alcohols and aldehydes in good yields. The reaction is highly diastereo- and regio-selective.

Keywords: highly diastereo; diastereo regio; synthesis dihydropyrans; regio selective

Journal Title: ACS Omega
Year Published: 2019

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