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Uniaxial Anisotropy in PEDOT:PSS Electrodes Enhances the Photocurrent at Oblique Incidence in Organic Solar Cells

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PEDOT:PSS is a well studied organic conductor, commonly used as a transparent electrode material in printed organic devices such as organic solar cells. PEDOT:PSS thin films are known to be uniaxially… Click to show full abstract

PEDOT:PSS is a well studied organic conductor, commonly used as a transparent electrode material in printed organic devices such as organic solar cells. PEDOT:PSS thin films are known to be uniaxially anisotropic and exhibit a lower extinction coefficient and lower refractive index in the out of plane direction. To determine the maximum attainable photocurrent in thin film solar cells, the optical power dissipation can be calculated by the transfer matrix method. However, until now the anisotropic properties of PEDOT:PSS films have not been included in the model. In this work we have included an uniaxial anisotropic treatment of PEDOT:PSS films. We investigate reversed and semitransparent solar cells, with aluminum and PEDOT:PSS respectively as the second electrode and PEDOT:PSS as the top electrode, as compared to devices with isotropic PEDOT:PSS electrodes. For p-polarized light at large oblique incidence the inclusion of anisotropy shows a gain of over 7% for the maximum photocurrent in reversed solar ...

Keywords: organic solar; pss; pss electrodes; pedot pss; solar cells

Journal Title: ACS Photonics
Year Published: 2018

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