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Superfast Adsorption–Disinfection Cryogels Decorated with Cellulose Nanocrystal/Zinc Oxide Nanorod Clusters for Water-Purifying Microdevices

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In outdoor activities and disaster environments, a portable microdevice is very important for the rapid purification of field drinking water. Smart cryogels were fabricated by one-pot copolymerization among acrylamide (AM)… Click to show full abstract

In outdoor activities and disaster environments, a portable microdevice is very important for the rapid purification of field drinking water. Smart cryogels were fabricated by one-pot copolymerization among acrylamide (AM) monomers, 2-(dimethylamino) ethyl methacrylate (DMAEMA) monomers, and cellulose nanocrystal/zinc oxide (CNC/ZnO) nanorod clusters through a simple ice-template method. The effect of nanohybrid contents on microstructural, thermal, swelling, and antibacterial properties of cryogels-ZnO was investigated. With the incorporation of 1 wt % CNC/ZnO, the cryogels showed macroporous-networked structures with a high porosity of 93% and homogeneous nanorod clusters on the macroporous wall. Cryogels-ZnO showed high mechanical strength in both dry and wet states, an adsorption capacity of 30.8 g/g, superfast adsorption time (2.5 s), and a stable swelling–deswelling ability after 10 cycles. Additionally, the adsorption capacity of cryogels-ZnO presented a dual temperature/pH response. Upon treatment...

Keywords: superfast adsorption; nanorod clusters; water; cellulose nanocrystal; zinc oxide; nanocrystal zinc

Journal Title: ACS Sustainable Chemistry & Engineering
Year Published: 2017

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