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An efficient UV-Vis-NIR responsive upconversion and plasmonic enhanced photocatalyst based on lanthanide-doped NaYF4/SnO2/Ag

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Efficiently reclaiming the utilization of solar light in the photocatalysis system remains very challenging. Integrating full advantage of upconversion material, plasmonic metal and narrow bandgap semiconductor, β-NaYF4:18%Yb3+, 2%Tm3+@SnO2@Ag nanoparticles (denoted… Click to show full abstract

Efficiently reclaiming the utilization of solar light in the photocatalysis system remains very challenging. Integrating full advantage of upconversion material, plasmonic metal and narrow bandgap semiconductor, β-NaYF4:18%Yb3+, 2%Tm3+@SnO2@Ag nanoparticles (denoted as NaYF4@SnO2@Ag NPs) are designed and successfully synthesized as wide-spectral (UV-Vis-NIR) responsive upconversion and plasmonic enhanced photocatalyst. The as-obtained NaYF4@SnO2@Ag NPs present broadband optical absorption dimension, excellent photocatalytic efficiency and good stability for the degradation of organic dyes. The enhanced photocatalytic performance of NaYF4@SnO2@Ag NPs can be attributed to the synergistic effects of the components composed in this core/shell architecture that result in higher photocarriers yield and favor the efficient transfer of photocarriers and energy. This work will give insight guidance of fabricating efficient, multi-component upconversion catalysts, and propose the potential in the field of high-effi...

Keywords: sno2; vis nir; responsive upconversion; nayf4 sno2; nir responsive

Journal Title: ACS Sustainable Chemistry & Engineering
Year Published: 2017

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