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Ca20Al26Mg3Si3O68:Ce3+,Tb3+ Phosphors: Preferential Site Occupation, Color-Tunable Luminescence and Device Application

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A novel luminescence material of emitting color-tunable Ca20Al26Mg3Si3O68 (denoted as CAMSO):Ce3+,Tb3+ phosphors have been synthesized via the high temperature solid-phase reaction process. The crystal cell structure, photoluminescence properties and application… Click to show full abstract

A novel luminescence material of emitting color-tunable Ca20Al26Mg3Si3O68 (denoted as CAMSO):Ce3+,Tb3+ phosphors have been synthesized via the high temperature solid-phase reaction process. The crystal cell structure, photoluminescence properties and application performance such as thermal stability and LED device performance of the phosphors were researched in detail. CAMSO:Ce3+,Tb3+ phosphors showed multicolor with the different concentration of Ce3+ and Tb3+ ions. Although the concentration of Ce3+ ions was settled and there was the existence of energy transfer from Ce3+ to Tb3+ ions, it was found that Ce3+ ions’ blue light emission intensity showed abnormal increasing with the increase of Tb3+ ions doping concentration. The irregular phenomenon was discussed in detail. The phosphor CAMSO:0.2Ce3+,0.1Tb3+ photoluminescence emission intensity motivated by 374 nm at 150 °C retained about 81% of that measured at room temperature, which demonstrating the good thermal and color stability of the sample. In ad...

Keywords: color tunable; ce3; tb3 phosphors; ce3 tb3

Journal Title: ACS Sustainable Chemistry & Engineering
Year Published: 2019

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