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Toward the Shell Biorefinery: Processing Crustacean Shell Waste Using Hot Water and Carbonic Acid

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Biomass fractionation is a prerequisite for almost any biorefinery process. Yet, a cost-effective and environmentally benign approach to separate biomass feedstock into valuable fractions remain a challenge. Herein we introduce… Click to show full abstract

Biomass fractionation is a prerequisite for almost any biorefinery process. Yet, a cost-effective and environmentally benign approach to separate biomass feedstock into valuable fractions remain a challenge. Herein we introduce a new fractionation method to extract high value chitin from crustacean shell (e.g., shrimp shell) using hot water for deproteinization and carbonic acid for demineralization (termed as the HOW-CA process). This method features high deproteinization and demineralization efficiencies (>90%), and the whole process is accomplished within hours. The desired final product chitin exhibits a high purity. This work addresses the major problems associated with the current industrial practice including the employment of corrosive reagents, the destructive removal of a useful component, and the generation of a large amount of waste. Economic and life-cycle analyses imply that the HOW-CA process is superior to the conventional method, offering both economic and environmental benefits.

Keywords: hot water; shell; biorefinery; crustacean shell; carbonic acid; using hot

Journal Title: ACS Sustainable Chemistry & Engineering
Year Published: 2019

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