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Multifunctional pH-Switched Superwetting Copolymer Nanotextile: Surface Engineered toward on-Demand Light Oil–Water Separation on Superhydrophilic–Underwater Low-Adhesive Superoleophobic Nonwoven Mesh

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The high performance of an oil–water separator relies largely on unique design of the architecture with a hierarchical and porous morphology as well as smart wetting responsiveness of active materials.… Click to show full abstract

The high performance of an oil–water separator relies largely on unique design of the architecture with a hierarchical and porous morphology as well as smart wetting responsiveness of active materials. A well-structured NaOH-treated antioil nonwoven mesh with in-situ and ex-situ pH-switched wetting was successfully prepared by controlled electrospinning of SAN copolymer followed by thermal treating in NaOH aqueous solution. The as-obtained robust and flexible pH-switched antioil mesh with highly accessible pH-responsive groups and a 3D open porous network geometry not only will achieve durable superhydrophilicity/superoleophobicity in air but also a superior underwater low-adhesive superoleophobicity could be obtained, leading the surface to be successfully used for long-term usage immiscible/emulsified light oil–water separation using only gravity-driven force with excellent antioil fouling during multiple cycles. Simultaneously, the water-soluble pollutant could be effectively captured by the antioil me...

Keywords: water; oil water; underwater low; nonwoven mesh; low adhesive

Journal Title: ACS Sustainable Chemistry & Engineering
Year Published: 2019

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