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The generation of tertiary, secondary, and primary alkyl radicals has been achieved by the direct visible-light excita-tion of a boracene-based alkylborate. This system is based on the photophysical properties of… Click to show full abstract
The generation of tertiary, secondary, and primary alkyl radicals has been achieved by the direct visible-light excita-tion of a boracene-based alkylborate. This system is based on the photophysical properties of the organoboron mole-cule. The protocol is applicable to decyanoalkylation, Giese addition, and nickel-catalyzed carbon-carbon bond for-mations such as alkyl-aryl cross-coupling or vicinal al-kylarylation of alkenes, enabling the introduction of vari-ous C(sp3) fragments to organic molecules.
Keywords:
alkyl radical;
generation alkyl;
boracene based;
based alkylborate
Journal Title: Journal of the American Chemical Society
Year Published: 2020
Link to full text (if available)
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Journal Title: Journal of the American Chemical Society
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!