Glassy phases of framework materials feature unique and tunable properties that are advantageous for gas separation membranes, solid electrolytes, and phase-change memory applications. Here, we report a new guanidinium organosulfonate… Click to show full abstract
Glassy phases of framework materials feature unique and tunable properties that are advantageous for gas separation membranes, solid electrolytes, and phase-change memory applications. Here, we report a new guanidinium organosulfonate hydrogen-bonded organic framework (HOF) that melts and vitrifies below 100 °C. In this low-temperature regime, non-covalent interactions between guest molecules and the porous framework become a dominant contributor to the overall stability of the structure, resulting in guest-dependent melting, glass, and recrystallization transitions. Through simulations and X-ray scattering, we show that the local structures of the amorphous liquid and glass phases resemble those of the parent crystalline framework.
               
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