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Benzoquinone Enhances Hyperpolarization of Surface Alcohols with Para-Hydrogen

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The nuclear singlet state of H2, para-hydrogen, can be used to increase the measurable signal-to-noise for magnetic resonance techniques—a form of hyperpolarization. Transfer of this polarization from para-hydrogen to alcohols… Click to show full abstract

The nuclear singlet state of H2, para-hydrogen, can be used to increase the measurable signal-to-noise for magnetic resonance techniques—a form of hyperpolarization. Transfer of this polarization from para-hydrogen to alcohols through surface interactions rather than formal hydrogenation has only been demonstrated on heterogeneous catalysts tailored to minimize loss of spin order. Here, we find that a common platinum-on-carbon catalyst is capable of this interaction and that the addition of a benzoquinone significantly increases the signal output of hyperpolarized methanol or water.

Keywords: enhances hyperpolarization; para hydrogen; benzoquinone enhances; hydrogen

Journal Title: Journal of the American Chemical Society
Year Published: 2023

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