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The first {Mn31} cluster (1) has been prepared from carboxylate ions and the chelating/bridging ligand α-methyl-2-pyridine-methanol. Compound 1 possesses a unique nanosized structural topology with one of the largest energy… Click to show full abstract
The first {Mn31} cluster (1) has been prepared from carboxylate ions and the chelating/bridging ligand α-methyl-2-pyridine-methanol. Compound 1 possesses a unique nanosized structural topology with one of the largest energy barriers reported to-date for high-nuclearity 3d-metal clusters. Single-crystal magnetic hysteresis studies reveal the presence of hysteresis loops below 5 K, one of the highest temperatures below which molecular hysteresis has been observed for 3d-based SMMs.
Keywords:
magnetic hysteresis;
transition metal;
energy;
hysteresis;
cluster
Journal Title: Journal of the American Chemical Society
Year Published: 2017
Link to full text (if available)
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Journal Title: Journal of the American Chemical Society
Year Published: 2017
Link to full text (if available)
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recommendations!